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| Ortisei $50,000 Carpet | Feb 3 2002 |
| Qual 1 | Julia Schruff - Santangelo | 7-5 6-1 |
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| Lecce $10,000 Clay | Feb 10 2002 |
| 1 | Isabella Mitterlehner - Santangelo(2) | 2-6 7-5 6-3 |
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| Las Palmas $10,000 Clay | Feb 24 2002 |
| 1 | Irena Nossenko-Q - Santangelo(1) | 7-5 3-6 1-0 |
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| Grado $25,000 Clay | Jun 16 2002 |
| 1 | Santangelo - Gloria Pizzichini(6) | 6-4 6-3 |
| 2 | Edina Gallovits - Santangelo | 1-6 6-0 6-3 |
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| Gorizia $25,000 Clay | Jun 23 2002 |
| Qual 1 | Santangelo(3) - Susanne Filipp | 6-1 6-1 |
| Qual 2 | Santangelo(3) - Urska Dobersek | 6-1 6-0 |
| Qual 3 | Ana Vrljic - Santangelo(3) | 1-6 6-3 6-1 |
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| Fontanafredda $25,000 Clay | Jun 30 2002 |
| 1 | Santangelo-WC - Magda Mihalache | 6-4 6-1 |
| 2 | Santangelo-WC - Maria Jose Martinez | 7-5 3-6 6-4 |
| QF | Santangelo-WC - Amandine Dulon | 7-65 6-4 |
| SF | Santangelo-WC - Yuliana Fedak | 6-3 6-1 |
| F | Alyona Bondarenko-Q - Santangelo-WC | 6-3 6-0 |
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| Modena $50,000 Clay | Jul 21 2002 |
| 1 | Alena Vaskova - Santangelo-WC | 6-3 7-5 |
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| Cesky Krumlov $25,000 Clay | Jul 28 2002 |
| 1 | Santangelo - Dessislava Topalova(8) | 6-2 6-3 |
| 2 | Santangelo - Katerina Bohmova-WC | 6-3 4-6 7-62 |
| QF | Sybille Bammer - Santangelo | 6-4 6-2 |
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| Brindisi $25,000 Clay | Aug 4 2002 |
| 1 | Santangelo - Joana Cortez | 6-2 6-1 |
| 2 | Zuzana Hejdova - Santangelo | 7-60 6-4 |
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| Aosta $25,000 Clay | Aug 18 2002 |
| 1 | Liga Dekmeijere - Santangelo | 6-4 6-4 |
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| Maribor $25,000 Clay | Aug 25 2002 |
| 1 | Santangelo - Meta Sevsek-WC | 6-1 6-0 |
| 2 | Santangelo - Marielle Hoogland | 6-0 3-6 6-2 |
| QF | Santangelo - Petra Russegger-Q | 6-4 3-1 |
| SF | Santangelo - Julia Schruff | 6-2 6-3 |
| F | Santangelo - Edina Gallovits(7) | 6-2 6-3 |
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| Fano $50,000 Clay | Sep 8 2002 |
| 1 | Santangelo-WC - Laurence Andretto | 6-3 6-2 |
| 2 | Santangelo-WC - Iveta Benesova(3) | 6-1 6-1 |
| QF | Santangelo-WC - Stanislava Hrozenska(8) | 4-6 6-4 6-2 |
| SF | Santangelo-WC - Edina Gallovits | 7-5 6-2 |
| F | Flavia Pennetta(5) - Santangelo-WC | 3-6 6-4 6-0 |
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| Biella $50,000 Clay | Sep 22 2002 |
| Qual 1 | Santangelo(3) - Giulia Gatto Monticone-WC | 6-0 4-6 6-0 |
| Qual 2 | Santangelo(3) - Kathrin Woerle | 6-4 6-1 |
| Qual 3 | Caroline Maes(8) - Santangelo(3) | 6-3 7-61 |
| 1 | Santangelo-LL - Stanislava Hrozenska | 6-0 6-2 |
| 2 | Santangelo-LL - Ludmila Cervanova(1) | 3-6 6-4 6-4 |
| QF | Andreea Vanc - Santangelo-LL | 2-6 6-3 6-0 |
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| Batumi $75,000 Hard | Sep 29 2002 |
| 1 | Santangelo - Galina Fokina(4) | 2-6 7-5 6-3 |
| 2 | Olha Lazarchuk-Q - Santangelo | 7-65 6-0 |
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| Cardiff $25,000 Hard | Oct 13 2002 |
| 1 | Anne Keothavong-Q - Santangelo | 6-3 6-2 |
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| Joue-Les-Tours $25,000 Hard | Oct 20 2002 |
| 1 | Santangelo(8) - Kyra Nagy | 7-63 0-6 6-3 |
| 2 | Santangelo(8) - Dessislava Topalova | 3-6 6-4 6-2 |
| QF | Santangelo(8) - Jasmin Woehr | 6-3 7-5 |
| SF | Santangelo(8) - Maret Ani(6) | walkover |
| F | Camille Pin(5) - Santangelo(8) | 2-6 6-3 6-0 |
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| Saint-Raphael $25,000 Hard | Oct 27 2002 |
| 1 | Santangelo - Dally Randriantefy(2) | 0-6 7-69 7-63 |
| 2 | Santangelo - Tzipora Obziler | 7-5 6-4 |
| QF | Santangelo - Sophie Lefevre-Q | 3-6 6-2 6-3 |
| SF | Severine Beltrame - Santangelo | 6-72 6-2 6-3 |